EXCESS-ENTHALPIES AND VOLUMES OF BINARY-MIXTURES OF 1-ALKENES WITH METHANOL AND WITH ETHANOL

被引：8

作者：

LETCHER, TM

SCHOONBAERT, FEZ

MERCERCHALMERS, J

PRASAD, AK

机构：

[1] Department of Chemistry, Rhodes University

来源：

THERMOCHIMICA ACTA | 1990年 / 171卷

关键词：

D O I：

10.1016/0040-6031(90)87015-5

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Molar excess enthalpies HEm have been determined using an LKB flow calorimeter, and molar excess volumes VEm using a Paar DMA 601 densitometer over the whole composition range, for all the binary mixtures of 1-hexene, 1-heptene and 1-octene with methanol and with ethanol at 298.15 K. The results were compared with HEm and VEm values for mixtures of an n-alkane with methanol and with ethanol in order to determine the effect of the double bond in the 1-alkene with alcohol mixtures. © 1990.

引用

页码：147 / 152

页数：6

共 14 条

[1]

BAGLEY EB, 1973, J PHYS CHEM-US, V77, P279

[2] TEMPERATURE-DEPENDENCE OF EXCESS THERMODYNAMIC PROPERTIES OF ETHANOL + NORMAL-HEPTANE AND 2-PROPANOL + NORMAL-HEPTANE SOLUTIONS [J].