COBALT(II) HALIDE-COMPLEXES WITH ETHYLENESELENOUREA

被引：10

作者：

DEVILLANOVA, FA

VERANI, G

机构：

[1] Istituto Chimico Policattedra, 09100 Cagliari

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 08期

关键词：

D O I：

10.1016/0022-1902(79)80466-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes obtained from ethyleneselenourea and cobalt(II) halides have been prepared and characterized. They have formula CoL2X2 (X = Cl, Br, I), tetrahedral stereochemistry and they are Se-bonded to the cobalt(II). They are comparatively studied with the previously reported complexes of cobalt(II) with ethylenethiourea, by IR and visible spectroscopy and magnetic susceptibilities. Using the average linand field approximation, the ethyleneselenourea is located at the very low end of the nephelauxetic series. © 1979.

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页码：1111 / 1114

页数：4

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