INTERACTIONS OF 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE WITH PENTAFLUOROBENZOIC ACID IN [H-2(3)]ACETONITRILE

被引：7

作者：

BRYCKI, B ^{[1
]}

BRZEZINSKI, B ^{[1
]}

GRECH, E ^{[1
]}

机构：

[1] TECH UNIV SZCZECIN,INST FUNDAMENTAL CHEM,PL-71065 SZCZECIN,POLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1991年 / 08期

关键词：

D O I：

10.1039/p29910001209

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

FTIR and H-1, C-13 and F-19 NMR spectroscopic studies on 1,8-bis(dimethylamino)naphthalene mixtures (1:1 and 1:2) with pentafluorobenzoic acid and FTIR studies of 1,8-bis(dimethylamino)-napthalene mixtures (1:1 and 1:2) with 2,3,5,6-tetrafluorobenzoic acid in acetonitrile have been performed. It was shown that 1,8-bis(dimethylamino)naphthalene with two molecules of acid forms homoconjugated anions and protonated 1,8-bis(dimethylamino)naphthalene. In the case of a 1:1 mixture of 1,8-bis(dimethylamino)naphthalene with pentafluorobenzoic acid, decarboxylation of the acid is observed at room temperature.

引用

页码：1209 / 1211

页数：3

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