STEREOSPECIFIC ADDITION OF ARYLTELLURIUM(IV) TRICHLORIDES TO 3-METHYLCYCLOHEXENE - THE X-RAY CRYSTAL-STRUCTURE OF P-ANISYL(TRANS-2-CHLORO-TRANS-3-METHYL-1-CYCLOHEXYL)TELLURIUM(IV) DICHLORIDE

被引：5

作者：

BORECKA, B ^{[1
]}

CAMERON, TS ^{[1
]}

MALIK, MA ^{[1
]}

SMITH, BC ^{[1
]}

机构：

[1] UNIV LONDON,BIRKBECK COLL,DEPT CHEM,LONDON WC1H 0PP,ENGLAND

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1994年 / 72卷 / 08期

关键词：

D O I：

10.1139/v94-234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryltellurium(IV) trichlorides react with 3-methyl-1-cyclohexene to give aryl(trans-2-chloro-trans-3-methyl-1-cuyclohexyl)tellurium(IV) dichlorides. The X-ray crystal structure of p-anisyl(trans-2-chloro-trans-3-methyl-1-cyclohexyl)tellurium(IV) dichloride is reported. Single crystals of p-MeOC(6)H(4)(trans-2-Cl-trans-3-MeC(6)H(9))TeCl2 are triclinic, space group P ($) over bar 1 (No. 2) with a = 10.419(2) Angstrom, b = 10.906(3) Angstrom, c = 8.285(3) Angstrom, alpha = 92.40(3)degrees, beta = 95.85(2)degrees, gamma = 61.71(3)degrees, V = 824.6 Angstrom(3), D(calcd) = 1.761 g cm(-1) for Z = 2. The structure was refined to R = 0.0444 (R(w) = 0.0458).

引用

页码：1844 / 1848

页数：5

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