ALKOXY CARBONYL-COMPLEXES OF PALLADIUM AND THEIR ROLE IN ALCOHOL CARBONYLATION

被引：95

作者：

RIVETTI, F

ROMANO, U

机构：

[1] Snamprogetti S.p.A. Direzione Ricerca e Sviluppo

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1978年 / 154卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)90871-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The behaviour of phosphinepalladium(II) complexes in methanol/carbon monoxide systems has been investigated. Pd(COOCH3)(OAc)(PPh3)2 and Pd (COOCH3)2(PPh3)2 have been isolated and characterized. A scheme is presented for the formation of oxalate esters in alcohol carbonylation in the presence of palladium complexes. © 1978.

引用

页码：323 / 326

页数：4

共 17 条

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