THERMODYNAMICS OF LITHIUM CHLORIDE AND LITHIUM BROMIDE IN PROPYLENE CARBONATE

被引：46

作者：

SALOMON, M

机构：

[1] National Aeronautics and Space Administration, Electronics Research Center, Cambridge

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 10期

关键词：

D O I：

10.1021/j100844a026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical cell Li|Li+, X-|TlX, Tl (Hg), where X = Cl or Br has been studied over a small temperature range in anhydrous propylene carbonate. The thermodynamic quantities ΔG°, ΔH°, and ΔS° have been evaluated and compared to other solvents such as water, N-methylformamide, and methanol. There appears to be widely differing behavior of cations and anions in these solvents where the dielectric constants vary from 30 to 182.

引用

页码：3299 / &

共 43 条

[1]

BAUKE FGK, 1969, J ELECTROCHEM SOC, V116, P34

[2] The mutual salting-out of ions [J].