SYNTHESIS OF TETRAALLYLMETHANE

被引：7

作者：

REEVE, W

BIANCHI, RJ

机构：

[1] Chemistry Department, University of Maryland, College Park

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 06期

关键词：

D O I：

10.1021/jo01258a087

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetraallylmethane has been synthesized by the following route: → triallylmethyl chloride → triallylmethylmagnesium chloride → tetraallylmethane via reaction with allyl bromide. Its stability is such that it can be kept for many months without polymerizing. An isomer of the tetraallylmethane is formed in the last step of the synthesis and is believed to be 4-allyl-4-vinyl-1,7-octadiene. It is presumed to be formed by the rearrangement of one homoallylic carbanion to an isomeric one through a cyclopropylmethyl carbanion intermediate. © 1969, American Chemical Society. All rights reserved.

引用

页码：1921 / &