Liquid phase nitrogen endor in nitroxide radicals

被引：44

作者：

Leniart, D. S. ^{[1
]}

Vedrine, J. C. ^{[1
]}

Hyde, J. S. ^{[1
]}

机构：

[1] Inst Rech Catalyse, CNRS, F-69 Villeurbanne, France

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 06期

关键词：

D O I：

10.1016/0009-2614(70)85246-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron-nuclear double resonance (ENDOR) signals have been observed from nitrogen nuclei of several nitroxide radicals in the liquid phase: The rf enhancement factor. which increases the effective radio frequency field at the nucleus by a factor of 21 in the present case, makes these observations Possible. Cross relaxation, arising from non-secular terms of the dipolar spectral density, is the dominant Delta m(1) approximate to 1 relaxation mechanism. The data are sufficiently precise that dynamic second order shifts of the observed ENDOR transitions must be considered.

引用

页码：637 / 640

页数：4

共 12 条

[1]

ABRAGAM A, 1961, PRINCIPLES NUCLEAR M, P194

[2] The interpretation of optically detected ENDOR in zero field and their relationship to N-14 nuclear quadrupole interactions in (3)(pi pi*) states of quinoline and quinoxaline [J].