GENERATION OF VINYLCARBENES BY THE INTRAMOLECULAR ADDITION OF ALPHA-DIAZO KETONES TO ACETYLENES

被引：76

作者：

PADWA, A

CHIACCHIO, U

GARREAU, Y

KASSIR, JM

KRUMPE, KE

SCHOFFSTALL, AM

机构：

[1] Department of Chemistry, Emory University, Atlanta

[2] Department of Chemistry, Universita di Catania, Catania

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 02期

关键词：

D O I：

10.1021/jo00289a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: Treatment of several a-diazo alkynyl substituted ketones with rhodium(II) carboxylates results in intramolecular addition to the acetylenic 7r-bond to give a transient cyclopropene which spontaneously rearranges to a vinyl carbene intermediate. © 1990, American Chemical Society. All rights reserved.

引用

页码：414 / 416

页数：3

共 32 条

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ARNOLD, DR
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LEIGH, WJ
PALMER, GE
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[10] HAUCK G, 1981, J CHEM RES-S, P180

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