POSSIBLE QUANTUM EFFECTS IN COLLISIONAL ENERGY-TRANSFER IN HIGHLY EXCITED MOLECULES

被引：11

作者：

GILBERT, RG ^{[1
]}

ZARE, RN ^{[1
]}

机构：

[1] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 05期

关键词：

D O I：

10.1016/0009-2614(90)85021-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It has been observed that classical trajectory calculations of energy transfer rates in large highly excited molecules with He bath gas give values much higher than experiment. This might be caused by quantum effects in which contributions from higher partial waves do not contribute to energy transfer. Experimental means of testing this postulate are proposed. © 1990.

引用

页码：407 / 411

页数：5

共 17 条

[1] BERNSTEIN RB, 1966, ADV CHEM PHYS, V10, P75
[2] THEORETICAL-STUDIES OF COLLISIONAL ENERGY-TRANSFER IN HIGHLY EXCITED MOLECULES - THE IMPORTANCE OF INTRAMOLECULAR VIBRATIONAL REDISTRIBUTION IN SUCCESSIVE COLLISION MODELING OF HE+CS2
BRUEHL, M
SCHATZ, GC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (02) : 770 - 779
[3] VIBRATIONAL-ENERGY TRANSFER IN COLLISIONS OF HE ATOMS WITH PARA-DIFLUOROBENZENE
CLARY, DC
[J]. JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (02) : 813 - 821
[4] A TIME-DEPENDENT WAVE PACKET APPROACH TO 3-DIMENSIONAL GAS SURFACE SCATTERING
DROLSHAGEN, G
HELLER, EJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (04) : 2072 - 2082
[5] COLLISIONAL ENERGY-TRANSFER OF VIBRATIONALLY HIGHLY EXCITED MOLECULES .6. ENERGY-DEPENDENCE OF (DELTA-E) IN AZULENE
HIPPLER, H
OTTO, B
TROE, J
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1989, 93 (04): : 428 - 434
[6] TRAJECTORY CALCULATIONS OF INTERMOLECULAR ENERGY-TRANSFER IN SO2-AR COLLISIONS .1. METHOD AND REPRESENTATIVE RESULTS
HIPPLER, H
SCHRANZ, HW
TROE, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (23) : 6158 - 6167
[7] HIPPLER H, 1989, BIMOLECULAR COLLISIO, P209
[8] Hirschfelder J. O., 1964, MOL THEORY GASES LIQ, V165
[9] COLLISION PARTNER AND LEVEL DEPENDENCE OF VIBRATIONAL-RELAXATION IN SO PARA-DIFLUOROBENZENE - STIMULATED-EMISSION PUMPING COMBINED WITH SINGLE VIBRONIC LEVEL FLUORESCENCE SPECTROSCOPY
KABLE, SH
THOMAN, JW
KNIGHT, AEW
[J]. JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (08) : 4748 - 4764
[10] KOHLMAIER GH, 1962, J CHEM PHYS, V38, P1692

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