EFFECTS OF POLARIZATION IN THE FIELD-IONIZATION SPECTRUM OF H2O

被引：39

作者：

GILBERT, RD

CHILD, MS

机构：

[1] Department of Theoretical Chemistry, University of Oxford, Oxford, OX1 3UB

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 187卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(91)90500-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Anomalous lines in the ZEKE field-ionization spectrum of H2O are explained via a mechanism of energy redistribution between core rotation and the Rydberg electron, mediated by the Rydberg-core-dipole interaction. A quantum defect model of the interaction, involving the coupling of two closed channels, is discussed in relation to predictions of the intensities of the observed lines. Experimental implications of this polarization mechanism are suggested.

引用

页码：153 / 160

页数：8

共 11 条

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