2-DIRECTIONAL CASCADE POLYMER SYNTHESIS - EFFECTS OF CORE VARIATION

被引：56

作者：

NEWKOME, GR

LIN, XF

YAXIONG, C

ESCAMILLA, GH

机构：

[1] Center for Molecular Design and Recognition, Department of Chemistry, University of South Florida, Tampa

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 11期

关键词：

D O I：

10.1021/jo00063a036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of two-directional arborols possessing spirane or biphenyl cores has been prepared in order to evaluate steric parameters in molecular packing necessary for aggregation. The core molecules were prepared by known procedures and structurally confirmed by H-1 and C-13 NMR spectra. The resultant arborols failed to aggregate in an aqueous environment supporting the computationally generated picture depicting the molecular interactions during the initial stages of gelation.

引用

页码：3123 / 3129

页数：7

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