IS THE EXTRA STABILITY OF ALKOXY ANIONS A RESULT OF A COILING EFFECT OR OF INTRAMOLECULAR HYDROGEN-BONDING

被引：10

作者：

CATALAN, J

机构：

[1] Departamento de Química Física Aplicada, Universidad Autónoma de Madrid

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 221卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(94)87018-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The coiling effect should not be invoked to account for the fact that the basicity of alkyl-amines and acidity of alkanols in the gas phase do not fall off as the chain length increases. For alkanols, the reason lies in the formation of an intramolecular hydrogen bond between a C-H group and the oxygen atom in the anion.

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页码：68 / 70

页数：3

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