THERMOGRAVIMETRIC KINETIC-STUDY OF THE PYROLYSIS OF MUNICIPAL SOLID-WASTE

被引:55
作者
GARCIA, AN
MARCILLA, A
FONT, R
机构
[1] Departmento de Ingeniería Quimica, Universidad de Alicante, Alicante
关键词
DTG; FLASH PYROLYSIS; KINETICS; PYROLYSIS; TGA; WASTE;
D O I
10.1016/0040-6031(94)02002-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
A kinetic study of the pyrolysis of municipal solid waste (MSW) was carried out by thermogravimetric analysis (TGA). Different runs were performed at heating rates between 1.5 and 200 degrees C min(-1). A correlation model that considers two independent reactions was applied to simulate the process. The values of the kinetic parameters were optimised and compared with the results obtained from the correlation of the experiments carried out in a Pyroprobe 1000, where the nominal heating rate was 20 000 degrees C s(-1). Tn view of the results obtained, a theoretical analysis was developed with reference to the influence of the heating rate and the heat transfer on the kinetic parameters that can be obtained from the experimental data.
引用
收藏
页码:277 / 304
页数:28
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