HYDROLYTIC CLEAVAGE OF TRIS(TRIMETHYLSIYL)-DERIVATIVES OF PHOSPHORUS ARSENIC AND ANTIMONY

被引：56

作者：

BURGER, H

GOETZE, U

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)88698-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cleavage of [(CH3)3Si]3M (M = P, As) by H2O, D2O, and CH3OH is a convenient method for the preparation of [(CH3)3Si]nMD(D)3-n compounds. The 1H NMR and the vibrational spectra suggest a pyramidal structure of all P, As, and Sb derivatives and do not support the presence of π interactions in the SiM bond. © 1968.

引用

页码：451 / &

共 14 条

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[8] BURGER H, IN PRESS
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