SYNTHESIS AND REACTIVITY OF A NEW ORGANOTIN HYDRIDE WITH POLAR TAIL - DIBUTYL-4,7,10-TRIOXAUNDECYLSTANNANE

被引：15

作者：

FERKOUS, F

MESSADI, D

DEJESO, B

DEGUEILCASTAING, M

MAILLARD, B

机构：

[1] UNIV BORDEAUX 1,CNRS,CHIM ORGAN & ORGANOMET LAB,351 COURS DE LA LIBERAT,F-33405 TALENCE,FRANCE

[2] UNIV ANNABA,CHIM LAB,ANNABA,ALGERIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86458-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new tin hydride was prepared by reduction of the tin chloride obtained in the addition of hydrogenochlorodibutylstannane to the allyl methyl ether of diethyleneglycol. The efficiency of this compound in reductions and reductive additions to alkenes of alkyl halides was demonstrated as well as the easy separation of the organic products of reaction from the organotin compounds by liquid-solid chromatography over silica.

引用

页码：315 / 320

页数：6

共 13 条

[1]

BERGE JM, 1979, SYNTHESIS-STUTTGART, P471

[2] SILANE TRIOLS OF HIGH STABILITY IN AQUEOUS-SOLUTION [J].