DEHYDROGENATIVE SILYLATION OF KETONES WITH A BIFUNCTIONAL ORGANOSILANE BY RHODIUM-PYBOX CATALYSTS

被引：20

作者：

NAGASHIMA, H ^{[1
]}

UEDA, T ^{[1
]}

NISHIYAMA, H ^{[1
]}

ITOH, K ^{[1
]}

机构：

[1] TOYOHASHI UNIV TECHNOL, DEPT MAT SCI, TOYOHASHI, AICHI 441, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 02期

关键词：

D O I：

10.1246/cl.1993.347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dehydrogenative silylation of ketones with 1,2-bis(dimethylsilyl)ethane is catalyzed by a mixture of RhCl3(pybox) and AgOTf to form the corresponding silylenol ether in high yields. Only one Si-H group of 1,2-bis(dimethylsilyl)ethane is converted to the corresponding silyl enol ether.

引用

页码：347 / 350

页数：4

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