BIOTRANSFORMATION OF (+/-)-4,8-DIMETHYLCYCLODECA-3(E),7(E)-DIEN-1-BETA-OL AND (+)-HEDYCARYOL BY CICHORIUM-INTYBUS

被引：18

作者：

PIET, DP ^{[1
]}

MINNAARD, AJ ^{[1
]}

VANDERHEYDEN, KA ^{[1
]}

FRANSSEN, MCR ^{[1
]}

WIJNBERG, JBPA ^{[1
]}

DEGROOT, A ^{[1
]}

机构：

[1] AGR UNIV WAGENINGEN,DEPT ORGAN CHEM,6703 HB WAGENINGEN,NETHERLANDS

来源：

TETRAHEDRON | 1995年 / 51卷 / 01期

关键词：

D O I：

10.1016/0040-4020(94)00938-Q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The biotransformation of the synthetic (E,E)-1,5-cyclodecadienol 5 and (+)-hedycaryol (11) by a root suspension of fresh chicory has been investigated. Incubation of 5 with a root suspension gave a 2:1 mixture of the epimeric eudesmanediols 7a and 7b whereas 11 was selectively converted into cryptomeridiol (12). An explanation for the obtained results is proposed.

引用

页码：243 / 254

页数：12

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