UV-IR DOUBLE-RESONANCE SPECTROSCOPY OF JET-COOLED PROPYNAL DETECTED BY THE FLUORESCENCE DIP METHOD

被引：34

作者：

WALTHER, T

BITTO, H

MINTON, TK

HUBER, JR

机构：

[1] Physikalisch-Chemisches Institut der Universität Zürich, CH-8057 Zurich

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 231卷 / 01期

关键词：

D O I：

10.1016/0009-2614(94)01224-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pulsed UV-IR double-resonance spectroscopy was implemented to demonstrate IR absorption spectroscopy in electronically excited polyatomic molecules by fluorescence dip detection, using jet-cooled propynal (HCCCHO) excited to the first excited singlet state S1 as an example. This method opens the possibility to study the spectroscopy and dynamics of rovibronic states which are not accessible in one-photon transitions or are non-fluorescing.

引用

收藏

页码：64 / 69

页数：6

相关论文

共 18 条

[1] THE INFRA-RED SPECTRUM OF PROPYNAL [J].

BRAND, JCD ;

WATSON, JKG .

TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (11) :1582-1590

[2]

BRAND JCD, 1963, DISCUSS FARADAY SOC, V35, P175

[3] ION DIP SPECTROSCOPY - A NEW TECHNIQUE OF MULTI-PHOTON IONIZATION SPECTROSCOPY APPLIED TO I2 [J].

COOPER, DE ;

KLIMCAK, CM ;

WESSEL, JE .

PHYSICAL REVIEW LETTERS, 1981, 46 (05) :324-328

[4] HIGHLY EXCITED-STATES OF NITRIC-OXIDE STUDIED BY 2-COLOR DOUBLE-RESONANCE SPECTROSCOPY [J].

EBATA, T ;

MIKAMI, N ;

ITO, M .

JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (03) :1132-1139

[5] EFFECTS OF CONFIGURATION INTERACTION ON INTENSITIES AND PHASE SHIFTS [J].

FANO, U .

PHYSICAL REVIEW, 1961, 124 (06) :1866-&

[6] RYDBERG STATES (N=4-29) OF AZABICYCLO [2.2.2] OCTANE AS STUDIED BY 2-COLOR FLUORESCENCE DIP AND MULTIPHOTON IONIZATION SPECTROSCOPIES [J].

FUJII, M ;

MIKAMI, N ;

ITO, M .

CHEMICAL PHYSICS, 1985, 99 (01) :193-206

[7] 2-COLOR MULTIPHOTON IONIZATION AND FLUORESCENCE DIP SPECTRA OF DIAZABICYCLO[2.2.2]OCTANE IN A SUPERSONIC FREE JET - RYDBERG STATES (N=5-39) AND AUTOIONIZATION [J].

FUJII, M ;

EBATA, T ;

MIKAMI, N ;

ITO, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (19) :4265-4271

[8] 2-COLOR FLUORESCENCE DIP AND MPI SPECTRA OF JET-COOLED PYRAZINE [J].

GOTO, A ;

FUJII, M ;

ITO, M .

CHEMICAL PHYSICS LETTERS, 1987, 135 (4-5) :407-412

[9]

HAMILTON CE, 1986, ANNU REV PHYS CHEM, V37, P493

[10] LASER SPECTROSCOPY OF LARGE POLYATOMIC-MOLECULES IN SUPERSONIC JETS [J].

ITO, M ;

EBATA, T ;

MIKAMI, N .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1988, 39 :123-147