SUM RULES FOR VARIATIONAL WAVEFUNCTIONS

被引：68

作者：

DALGARNO, A

EPSTEIN, ST

机构：

[1] Harvard College Observatory, Smithsonian Astrophysical Observatory, Cambridge

[2] Theoretical Chemistry Institute, University of Wisconsin, Madison, WI

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 07期

关键词：

D O I：

10.1063/1.1671472

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is demonstrated that the finite set of wavefunctions obtained by applying the variational principle to a linear combination of basis functions provides bonds to a number of sum rules and that by appropriate choice of the basis functions certain of the sum rules can be satisfied exactly.

引用

页码：2837 / &

共 6 条

[1]

[Anonymous], ADV QUANTUM CHEM

[2] DIPOLE SPECTRUM AND PROPERTIES OF HELIUM [J].