TRANSITION STRUCTURE FOR THE [2,3]-WITTIG REARRANGEMENT AND ANALYSIS OF STEREOSELECTIVITIES

被引:95
作者
WU, YD
HOUK, KN
MARSHALL, JA
机构
[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024
[2] UNIV S CAROLINA,DEPT CHEM,COLUMBIA,SC 29208
关键词
D O I
10.1021/jo00292a007
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
: The transition structures for Wittig rearrangements of allyl lithiomethyl ether and substituted derivatives, located with ab initio molecular orbital calculations, provide a new hypothesis to account for the stereochemistries of these reactions. © 1990, American Chemical Society. All rights reserved.
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页码:1421 / 1423
页数:3
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