A PAN ANALOG FROM ISOPRENE PHOTOOXIDATION

被引：42

作者：

BERTMAN, SB ^{[1
]}

ROBERTS, JM ^{[1
]}

机构：

[1] BROOKHAVEN NATL LAB,DIV CRYPTOGAMIE,UPTON,NY 11973

来源：

GEOPHYSICAL RESEARCH LETTERS | 1991年 / 18卷 / 08期

关键词：

D O I：

10.1029/91GL01852

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

Peroxymethacrylic nitric anhydride (MPAN), a potential atmospheric photoproduct, was synthesized and characterized in the laboratory for the first time. The compound was identified by FT-IR, GC-MS, GC/ECD, and decomposition studies. Purification of synthetic mixtures provided a sample suitable for calibration of instruments for ambient atmospheric sampling. Possible field identification of MPAN is reported, and the role of MPAN in the chemistry of the rural troposphere is discussed.

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页码：1461 / 1464

页数：4

相关论文

共 29 条

[1] THE EFFECTS OF BIOGENIC HYDROCARBONS ON THE TRANSFORMATION OF NITROGEN-OXIDES IN THE TROPOSPHERE [J].

ATHERTON, CS ;

PENNER, JE .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D9) :14027-14038

[2] EVIDENCE FOR GREATER-THAN-OR-EQUAL-TO-C-3 ALKYL NITRATES IN RURAL AND REMOTE ATMOSPHERES [J].

ATLAS, E .

NATURE, 1988, 331 (6155) :426-428

[3] CONTRIBUTION OF ORGANIC NITRATES TO THE TOTAL REACTIVE NITROGEN BUDGET AT A RURAL EASTERN UNITED-STATES SITE [J].

BUHR, MP ;

PARRISH, DD ;

NORTON, RB ;

FEHSENFELD, FC ;

SIEVERS, RE ;

ROBERTS, JM .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D7) :9809-9816

[4] THE ROLE OF BIOGENIC HYDROCARBONS IN URBAN PHOTOCHEMICAL SMOG - ATLANTA AS A CASE-STUDY [J].

CHAMEIDES, WL ;

LINDSAY, RW ;

RICHARDSON, J ;

KIANG, CS .

SCIENCE, 1988, 241 (4872) :1473-1475

[5] REACTIVE NITROGEN SPECIES IN THE TROPOSPHERE - MEASUREMENTS OF NO, NO2, HNO3, PARTICULATE NITRATE, PEROXYACETYL NITRATE (PAN), O-3, AND TOTAL REACTIVE ODD NITROGEN (NOY) AT NIWOT RIDGE, COLORADO [J].

FAHEY, DW ;

HUBLER, G ;

PARRISH, DD ;

WILLIAMS, EJ ;

NORTON, RB ;

RIDLEY, BA ;

SINGH, HB ;

LIU, SC ;

FEHSENFELD, FC .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1986, 91 (D9) :9781-9793

[6] A GROUND-BASED INTERCOMPARISON OF NO, NOX, AND NOY MEASUREMENT TECHNIQUES [J].

FEHSENFELD, FC ;

DICKERSON, RR ;

HUBLER, G ;

LUKE, WT ;

NUNNERMACKER, LJ ;

WILLIAMS, EJ ;

ROBERTS, JM ;

CALVERT, JG ;

CURRAN, CM ;

DELANY, AC ;

EUBANK, CS ;

FAHEY, DW ;

FRIED, A ;

GANDRUD, BW ;

LANGFORD, AO ;

MURPHY, PC ;

NORTON, RB ;

PICKERING, KE ;

RIDLEY, BA .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D12) :14710-14722

[7] AN IMPROVED PROCEDURE FOR HIGH-PURITY GASEOUS PEROXYACYL NITRATE PRODUCTION - USE OF HEAVY LIPID SOLVENTS [J].

GAFFNEY, JS ;

FAJER, R ;

SENUM, GI .

ATMOSPHERIC ENVIRONMENT, 1984, 18 (01) :215-218

[8] AN INTERCOMPARISON OF AIRBORNE PAN MEASUREMENTS [J].

GREGORY, GL ;

HOELL, JM ;

RIDLEY, BA ;

SINGH, HB ;

GANDRUD, B ;

SALAS, LJ ;

SHETTER, J .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1990, 95 (D7) :10077-10087

[9]

Heller S.R., 1978, EPA NIH MASS SPECTRA

[10] PHOTOCHEMISTRY OF BIOGENIC EMISSIONS OVER THE AMAZON FOREST [J].

JACOB, DJ ;

WOFSY, SC .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1988, 93 (D2) :1477-1486