Electrolyte Conductivity of Salts in Hexamethylphosphotriamide

被引：49

作者：

Hanna, E. M.

Pethybridge, A. D. ^{[1
]}

Prue, J. E. ^{[1
]}

Spiers, D. J. ^{[1
]}

机构：

[1] Univ Reading, Dept Chem, Reading RG6 2AD, Berks, England

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1974年 / 3卷 / 08期

关键词：

Electrolytic conductivity; alkali metal salts; hexamethylphosphotriamide; association;

D O I：

10.1007/BF00650401

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Precise conductivity measurements are reported for twenty-two 1:1 salts in hexamethylphosphotriamide at 25 degrees C. The results have been analyzed using the full versions of the equations of Fuoss-Hsia and of Pitts for the conductivity of the free ions. The K-A and Lambda(infinity) values are consistent with strong cation solvation but weak anion solvation by the solvent. Earlier results for salts in related solvents have been reanalyzed for comparative purposes.

引用

页码：563 / 583

页数：21

共 28 条

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