THE RATES OF A DIELS-ALDER REACTION IN LIQUID AND SUPERCRITICAL CARBON-DIOXIDE

被引：37

作者：

ISAACS, NS

KEATING, N

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 12期

关键词：

D O I：

10.1039/c39920000876

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic measurements on the Diels-Alder reaction between p-benzoquinone and cyclopenta-1,3-diene have been carried out in carbon dioxide as a medium between 25 and 40-degrees-C; the reaction effectively occurs throughout liquid and supercritical ranges with no discontinuity and rates are about 20% greater than those in diethyl ether.

引用

页码：876 / 877

页数：2

共 4 条

[1] BROGLE H, 1982, CHEM IND-LONDON, P385
[2] ISAACS NS, 1981, LIQUID PHASE HIGH PR, pCH4
[3] ADJUSTMENT OF THE SELECTIVITY OF A DIELS-ALDER REACTION NETWORK USING SUPERCRITICAL FLUIDS
KIM, S
JOHNSTON, KP
[J]. CHEMICAL ENGINEERING COMMUNICATIONS, 1988, 63 : 49 - 59
[4] REACTIONS IN SUPERCRITICAL FLUIDS - A CASE-STUDY OF THE THERMODYNAMIC SOLVENT EFFECTS ON A DIELS-ALDER REACTION IN SUPERCRITICAL CARBON-DIOXIDE
PAULAITIS, ME
ALEXANDER, GC
[J]. PURE AND APPLIED CHEMISTRY, 1987, 59 (01) : 61 - 68

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