FACILE SYNTHESIS OF (1,2-DIHYDROBENZOXAZOL-2-YLIDENE)TETRACARBONYLIRON COMPLEXES FROM 2-TRIMETHYLSILOXYPHENYL ISOCYANIDE

被引:54
作者
HAHN, FE
TAMM, M
机构
关键词
D O I
10.1039/c39930000842
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of 2-trimethylsiloxyphenyl isocyanide 3 with Fe(CO)5 and subsequent cleavage of the Si-O bond gives (1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 6, the structure of which has been determined by X-ray crystallography; complex 6 can be alkylated at the ring nitrogen yielding (N-methyl-1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 7.
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页码:842 / 844
页数:3
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