FACILE SYNTHESIS OF (1,2-DIHYDROBENZOXAZOL-2-YLIDENE)TETRACARBONYLIRON COMPLEXES FROM 2-TRIMETHYLSILOXYPHENYL ISOCYANIDE

被引：54

作者：

HAHN, FE

TAMM, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 10期

关键词：

D O I：

10.1039/c39930000842

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2-trimethylsiloxyphenyl isocyanide 3 with Fe(CO)5 and subsequent cleavage of the Si-O bond gives (1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 6, the structure of which has been determined by X-ray crystallography; complex 6 can be alkylated at the ring nitrogen yielding (N-methyl-1,2-dihydrobenzoxazol-2-ylidene)tetracarbonyliron 7.

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页码：842 / 844

页数：3

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