HEAT-TRANSPORT LIMITATIONS AND REACTION SCHEME OF PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS OVER SUPPORTED RHODIUM CATALYSTS

被引：47

作者：

BOUCOUVALAS, Y

ZHANG, ZL

VERYKIOS, XE

机构：

[1] Institute of Chemical Engineering and High Temperature Chemical Processes, Department of Chemical Engineering, University of Patras, Patras

来源：

CATALYSIS LETTERS | 1994年 / 27卷 / 1-2期

关键词：

METHANE OXIDATION; SYNTHESIS GAS; RHODIUM CATALYST; HEAT TRANSPORT;

D O I：

10.1007/BF00806986

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The partial oxidation of methane to synthesis gas over supported Rh catalysts is investigated, paying particular attention to removing heat transport limitations and identifying the reaction conditions within the kinetic-controlling regime. The results obtained suggest that the reaction follows the sequence of total oxidation to CO2 and H2O, followed by reforming reactions to synthesis gas.

引用

页码：131 / 142

页数：12

共 18 条

[1] SELECTIVE OXIDATION OF METHANE TO SYNTHESIS GAS-USING TRANSITION-METAL CATALYSTS
ASHCROFT, AT
CHEETHAM, AK
FOORD, JS
GREEN, MLH
GREY, CP
MURRELL, AJ
VERNON, PDF
[J]. NATURE, 1990, 344 (6264) : 319 - 321
[2] BIDIRECTIONAL ADIABATIC SYNTHESIS GAS GENERATOR
BLANKS, RF
WITTRIG, TS
PETERSON, DA
[J]. CHEMICAL ENGINEERING SCIENCE, 1990, 45 (08) : 2407 - 2413
[3] PARTIAL OXIDATION OF METHANE TO SYNGAS OVER CO/MGO CATALYSTS - IS IT LOW-TEMPERATURE
CHANG, YF
HEINEMANN, H
[J]. CATALYSIS LETTERS, 1993, 21 (3-4) : 215 - 224
[4] LOW-TEMPERATURE OXIDATIVE CONVERSION OF METHANE TO SYNGAS OVER NIO-CAO CATALYST
CHOUDHARY, VR
RAJPUT, AM
PRABHAKAR, B
[J]. CATALYSIS LETTERS, 1992, 15 (04) : 363 - 370
[5] LOW-TEMPERATURE CATALYTIC SELECTIVE PARTIAL OXIDATION OF METHANE TO CO AND H-2 OVER NI/YB2O3
CHOUDHARY, VR
RAJPUT, AM
RANE, VH
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (22) : 8686 - 8688
[6] NONEQUILIBRIUM OXIDATIVE CONVERSION OF METHANE TO CO AND H-2 WITH HIGH SELECTIVITY AND PRODUCTIVITY OVER NI/AL2O3 AT LOW-TEMPERATURES
CHOUDHARY, VR
RAJPUT, AM
PRABHAKAR, B
[J]. JOURNAL OF CATALYSIS, 1993, 139 (01) : 326 - 328
[7] LOW-TEMPERATURE OXIDATIVE CONVERSION OF METHANE TO SYNTHESIS GAS OVER CO RARE-EARTH-OXIDE CATALYSTS
CHOUDHARY, VR
RAJPUT, AM
RANE, VH
[J]. CATALYSIS LETTERS, 1992, 16 (03) : 269 - 272
[8] PARTIAL OXIDATION OF METHANE TO CARBON-MONOXIDE AND HYDROGEN OVER A NI/AL2O3 CATALYST
DISSANAYAKE, D
ROSYNEK, MP
KHARAS, KCC
LUNSFORD, JH
[J]. JOURNAL OF CATALYSIS, 1991, 132 (01) : 117 - 127
[9] DISSANAYAKE D, 1993, J PHYS CHEM-US, V97, P36644
[10] ACTIVATION OF CH4 AND ITS REACTION WITH CO2 OVER SUPPORTED RH CATALYSTS
ERDOHELYI, A
CSERENYI, J
SOLYMOSI, F
[J]. JOURNAL OF CATALYSIS, 1993, 141 (01) : 287 - 299

← 1 2 →