STUDIES IN GROUP 4 ORGANOMETALLIC CHEMISTRY .29. MECHANISM OF HYDROSTANNATION OF STRONGLY ELECTROPHILIC CARBONYL COMPOUNDS

被引：18

作者：

LEUSINK, AJ

BUDDING, HA

DRENTH, W

机构：

[1] Institute for Organic Chemistry TNO, Utrecht

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 13卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)88868-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mechanism of the hydrostannation of strongly electrophilic carbonyl compounds has been studied. From the kinetics, and the solvent and substituent effects, it appears that the addition reaction proceeds by nucleophilic attack of the hydride hydrogen on carbon. Further aspects of this and secondary reactions are discussed. © 1968.

引用

页码：163 / &

共 8 条

[1] COMPLEX FORMATION BY FLUOROKETONES .I. ADDITION OF HEXAFLUOROACETONE TO HYDRIDES OF GROUP 4 ELEMENTS
CULLEN, WR
STYAN, GE
[J]. INORGANIC CHEMISTRY, 1965, 4 (10) : 1437 - &
[2] ORGANOMETALLIC REACTIONS .6. ADDITION OF SN-O BOND TO CARBONYL GROUP
DAVIES, AG
SYMES, WR
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (10): : 1009 - &
[3] STUDIES IN GROUP 4 ORGANOMETALLIC CHEMISTRY .28. STRUCTURE OF PRODUCTS OBTAINED IN HYDROSTANNATION OF STRONGLY ELECTROPHILIC CARBONYL COMPOUNDS
LEUSINK, AJ
BUDDING, HA
MARSMAN, JW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 13 (01) : 155 - &
[4] LEUSINK AJ, 1966, RECL TRAV CHIM PAY-B, V85, P151
[5] STUDIES IN GROUP 4 ORGANOMETALLIC CHEMISTRY .25. NUCLEOPHILIC TRANS-ADDITION OF ORGANOTIN HYDRIDES TO CARBON-CARBON TRIPLE BONDS
LEUSINK, AJ
BUDDING, HA
DRENTH, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 9 (02) : 295 - &
[6] LEUSINK AJ, 1966, THESIS STATE U UTREC
[7] LEUSINK AJ, 1966, TETRAHEDRON LETT, P335
[8] NEUMANN WP, 1965, JUSTUS LIEBIGS ANN C, V683, P11

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