POTENTIAL-ENERGY CURVES FOR NO+

被引:139
作者
ALBRITTON, DL [1 ]
SCHMELTEKOPF, AL [1 ]
ZARE, RN [1 ]
机构
[1] STANFORD UNIV, DEPT CHEM, STANFORD, CA 94305 USA
关键词
D O I
10.1063/1.438757
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In recent years, high-resolution photoelectron spectroscopy and ab initio calculations have considerably revised and enlarged the understanding of the electronic structure of the NO+ ion. Based on these results, new potential energy curves for the electronic states of NO+ below 24 eV have been constructed and are given here. RKR potentials were calculated from new molecular constants for the eight experimentally well-defined states. For the other states, the main features of the potentials were estimated from theoretical calculations and from isoelectronic analogies. A brief review is given of the information on which each potential energy curve is based. © 1979 American Institute of Physics.
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页码:3271 / 3279
页数:9
相关论文
共 65 条
[1]   LABORATORY DETERMINATION OF FREQUENCIES OF POSSIBLE INTERSTELLAR LINES OF NO+ [J].
ALBERTI, F ;
DOUGLAS, AE .
CANADIAN JOURNAL OF PHYSICS, 1975, 53 (12) :1179-1181
[2]  
Albritton D. L., 1976, MOL SPECTROSCOPY MOD, P1
[3]   DOUBLE CHARGE-TRANSFER SPECTROSCOPY OF DIATOMIC-MOLECULES [J].
APPELL, J ;
DURUP, J ;
FEHSENFELD, FC ;
FOURNIER, P .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1973, 6 (01) :197-205
[4]  
BAER P, 1953, HELV PHYS ACTA, V26, P91
[5]   BAND SPECTRA IN THE SCHUMANN REGION OF NO AND N2+ WITH ENRICHED NITROGEN-15 [J].
BAER, P ;
MIESCHER, E .
NATURE, 1952, 169 (4301) :581-581
[6]  
BRION H, 1959, J CHEM PHYS, V30, P673
[7]   NOTE ON 5SIGMA+G STATE OF N2 [J].
CARROLL, PK .
JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (04) :805-&
[8]  
CERMAK V, 1966, J CHEM PHYS, V44, P3781
[9]  
COHEN ER, 1973, J PHYS CHEM REF DATA, V2, P741
[10]   Electronic states of the nitric oxide ion [J].
Collin, J. E. ;
Natalis, P. .
CHEMICAL PHYSICS LETTERS, 1968, 2 (03) :194-196