FUNCTIONAL OLIGOMERS OF NORBORNENE .2. KINETICS AND MECHANISM OF THE OLIGOMERIZATION REACTION

被引：7

作者：

CRAMAIL, H ^{[1
]}

FONTANILLE, M ^{[1
]}

SOUM, A ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,CHIM POLYMERES ORGAN LAB,F-33405 TALENCE,FRANCE

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 42-3卷

关键词：

D O I：

10.1002/masy.19910420123

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A comprehensive study of initiation and propagation steps of norbornene oligomerization initiated by WCl6/Me4Sn in the presence of unsaturated diesters, was carried out. Kinetic orders, apparent rate constants and thermodynamic parameters were determined. Given the experimental results, a mechanism of both initiation and propagation reactions is proposed.

引用

页码：281 / 292

页数：12

共 12 条

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