SOLVOLYSIS OF PALLADIUM(II) AND PLATINUM(II) COMPLEXES OF ASYMMETRIC LIGANDS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [PD(AMP)(DMSO)CL]BF4 AND [PT(AMP)(DMSO)CL]CLO4

被引：20

作者：

ALALLAF, T

CASTAN, P

TURPIN, R

WIMMER, S

WIMMER, S

BERNARDINELLI, G

机构：

[1] UNIV TOULOUSE 3,CHIM INORGAN LAB,118 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE

[2] LAB CRISTALLOG,GENEVA,SWITZERLAND

来源：

TRANSITION METAL CHEMISTRY | 1992年 / 17卷 / 06期

关键词：

D O I：

10.1007/BF02910763

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [M(AMP)Cl2] (M = Pt(II), Pd(II); AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO4, BF4, PF6) in dmso yields [M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the Pd(II) and Pt(II) complexes indicate that dmso is S-bonded trans to the pyridyl ring in both complexes.

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页码：579 / 582

页数：4

相关论文

共 38 条

[1] MODE OF BINDING OF DIMETHYL-SULFOXIDE IN PLATINUM(II) AND PALLADIUM(II) CATIONIC COMPLEXES CONTAINING A CHELATED DIAMINE - X-RAY CRYSTAL-STRUCTURES OF (2,2'-BIPYRIDYL)CHLORO(DIMETHYL SULFOXIDE-O)PALLADIUM(II) TETRAFLUOROBORATE AND CHLORO(DIMETHYL SULPHOXIDE-S)(ETHYLENEDIAMINE)PALLADIUM(II) PERCHLORATEY [J].

ANNIBALE, G ;

CATTALINI, L ;

BERTOLASI, V ;

FERRETTI, V ;

GILLI, G ;

TOBE, ML .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (07) :1265-1271

[2] KINETICS AND MECHANISM OF THE REACTION BETWEEN DIMETHYLSULFOXIDE AND DICHLORO(PYRIDINE-2-CARBOXYLATO)PLATINATE(II) ANION AND THE CIS-TRANS ISOMERIZATION OF THE PRODUCTS - X-RAY CRYSTAL-STRUCTURE OF TRANS-(O,S)-CHLORO(DIMETHYL SULPHOXIDE)(PYRIDINE-2-CARBOXYLATO)PLATINUM(II) [J].

ANNIBALE, G ;

CATTALINI, L ;

CANOVESE, L ;

PITTERI, B ;

TIRIPICCHIO, A ;

CAMELLINI, MT ;

TOBE, ML .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (06) :1101-1105

[3]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[4] REACTIONS OF PLATINUM(II) AQUA COMPLEXES .2. PT-195 NMR-STUDY OF REACTIONS BETWEEN THE TETRAAQUAPLATINUM(II) CATION AND CHLORIDE, HYDROXIDE, PERCHLORATE, NITRATE, SULFATE, PHOSPHATE, AND ACETATE [J].

APPLETON, TG ;

HALL, JR ;

RALPH, SF ;

THOMPSON, CSM .

INORGANIC CHEMISTRY, 1984, 23 (22) :3521-3525

[5]

Davis J. A., 1981, ADV INORG CHEM, V24, P115

[6]

FAGIANI R, 1977, INORG CHEM, V17, P1941

[7]

FAGIANI R, 1977, J AM CHEM SOC, V99, P777

[8]

FAGIANI R, 1977, INORG CHEM, V16, P1192

[9] RAPID INVERSION VERSUS STABLE CHIRAL CENTER FORMATION - DIFFERENT BEHAVIOR OF COORDINATED NITROGENS IN 4-COORDINATE AND 5-COORDINATE PLATINUM(II) COMPLEXES WITH N,N'-DISUBSTITUTED ETHYLENEDIAMINES [J].

FANIZZI, FP ;

MARESCA, L ;

NATILE, G ;

LANFRANCHI, M ;

MANOTTILANFREDI, AM ;

TIRIPICCHIO, A .

INORGANIC CHEMISTRY, 1988, 27 (14) :2422-2431

[10] CHEMICAL-PROPERTIES AND ANTITUMOR-ACTIVITY OF COMPLEXES OF PLATINUM CONTAINING SUBSTITUTED SULFOXIDES [PTCL(R'R''SO)(DIAMINE)]NO3 - CHIRALITY AND LEAVING-GROUP ABILITY OF SULFOXIDE AFFECTING BIOLOGICAL-ACTIVITY [J].

FARRELL, N ;

KILEY, DM ;

SCHMIDT, W ;

HACKER, MP .

INORGANIC CHEMISTRY, 1990, 29 (03) :397-403

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