SOLUBLE (CHLOROSILYL)PHOSPHINE AND SILOXYPHOSPHINE COMPLEXES OF RHODIUM(I)

被引：14

作者：

BRZEZINSKA, ZC ^{[1
]}

CULLEN, WR ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1W5,BC,CANADA

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1021/ic50201a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of soluble (chlorosilyl)phosphine complexes of rhodium(I) which are capable of being polymerized into poly(siloxyphosphine)-rhodium(I) species have been synthesized and characterized. They are L2‘Rh(CO)Cl, L‘3RhCl, L‘3RhCl, and L‘4Rh2Cl2 (L‘ = Cl3Si(CH2)2P(C6H5)2, L‘ = Cl3Si(CH2)8P(C6H5)2). Soluble siloxyphosphine-rhodium(I) complexes LRh(NBD)Cl, L2Rh(CO)Cl, L3RhCl, and L4Rh2Cl2 (NBD = norbornadiene, L = [(CH3)3SiO]2(CH3)Si-(CH2)2P(C6HS)2) have also been synthesized and characterized and their reactions with gaseous H2, CO, and HC1 as well as their catalytic behavior in hydrogenation reactions have been studied. These complexes were prepared to serve as study models for their polymeric counterparts. © 1979, American Chemical Society. All rights reserved.

引用

页码：3132 / 3138

页数：7

共 39 条

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