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SURFACE-ENHANCED RAMAN-SCATTERING USED AS AN IN-SITU ANALYTICAL METHOD FOR STUDIES OF POLYMER-METAL INTERFACE

被引：14
作者：
XUE, G
LU, Y
SHI, G
机构：
[1] Department of Chemistry, The Coordination Chemistry State Key Laboratory, Nanjing University, Nanjing
来源：
POLYMER | 1994年 / 35卷 / 12期
基金：
中国国家自然科学基金;
关键词：
POLYMER-METAL INTERFACE; ADSORPTION; CATALYSIS;
D O I：
10.1016/0032-3861(94)90368-9
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Physicochemical phenomena at the polymer-metal interface have been observed by the use of surface-enhanced Raman scattering (SERS). SERS spectra are compared with the infra-red reflection-absorption spectra for coatings of polymer on metals. Results show that SERS is an effective in situ analytical technique which is highly informative in that the authentic adsorption state and the microstructure of the first monolayer near the metal surface can be revealed with much less interference from the polymer bulk.
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页码：2488 / 2494
页数：7
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