TITANOCENE IMIDO COMPLEXES - GENERATION AS REACTIVE INTERMEDIATES, ISOLATION, AND STRUCTURAL CHARACTERIZATION

被引：21

作者：

DOXSEE, KM ^{[1
]}

GARNER, LC ^{[1
]}

JULIETTE, JJJ ^{[1
]}

MOUSER, JKM ^{[1
]}

WEAKLEY, TJR ^{[1
]}

HOPE, H ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

TETRAHEDRON | 1995年 / 51卷 / 15期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4020(94)01122-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitriles react with 2,3-dimethyl-1,1-bis(cyclopentadienyl)ti to afford either azatitanacyclohexadienes or diazatitanacyclooctatrienes. The latter appear to be formed via the intermediacy of butadienylimido complexes, which can be intercepted by the addition of trimethylphosphine. Bis(cyclopentadienyl)titanium bis(trimethylphosphine) undergoes ligand substitution reactions with nitriles. Loss of trimethylphosphine from the 2,4,6-trimethylbenzonitrile complex appears to lead to reductive coupling of the nitrile, affording a dimeric imido complex.

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页码：4321 / 4332

页数：12

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