SYNTHESIS OF BIS(N-METHYLIMIDAZOL-2-YL)KETONE (BIK) AND CRYSTAL-STRUCTURE OF [ZN(BIK)(2)](CLO4)(2)

被引：21

作者：

CHEN, XM ^{[1
]}

XU, ZT ^{[1
]}

MAK, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG

来源：

POLYHEDRON | 1995年 / 14卷 / 02期

关键词：

D O I：

10.1016/0277-5387(94)00340-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel polyimidazole ligand bis(N-methylimidazol-2-yl)ketone (BIK) has been synthesized and its first metal complex [Zn(BIK)(2)](ClO4)(2) has been structurally established by X-ray crystallography. The zinc atom is coordinated by two chelating BIK ligands in a distorted tetrahedral N-4 environment with Zn-N bonds at 1.997(8) Angstrom and N-Zn-N bond angles at 93.5(5)-137.3(5)degrees.

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页码：319 / 322

页数：4

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