RHODIUM(I)-CATALYZED ASYMMETRIC HYDROBORATION OF ALKENES WITH 1,3,2-BENZODIOXABOROLE

被引：95

作者：

SATO, M ^{[1
]}

MIYAURA, N ^{[1
]}

SUZUKI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV,FAC ENGN,DEPT APPL CHEM,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)94379-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several rhodium(I) complexes containing chiral phosphine, (+) DIOP, (+) BINAP, (S,S) CHIRAPHOS, and (S)(R) BPPFA, have been found to be effective as catalyst for the asymmetric hydroboration of prochiral alkenes with catecholborane (1,3,2-benzodioxaborole) to give optically active 2-alkyl-l,3,2-benzodioxaboroles. Among the ligands examined, DIOP has been recognized to be most effective to give high asymmetric induction. © 1990.

引用

页码：231 / 234

页数：4

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