ASYMMETRIC SELECTION VIA ADDITION .2. OPTICALLY-ACTIVE SULFOXIMIDES

被引:22
作者
ANNUNZIATA, R [1 ]
CINQUINI, M [1 ]
机构
[1] UNIV MILAN,IST CHIM IND,I-20133 MILAN,ITALY
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 07期
关键词
D O I
10.1039/p19790001684
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The kinetic resolution of the unsaturated sulphoximides (6)-(10) via addition of the chiral amines (11)-(13) has been examined. The rate of reaction depends strongly on steric effects, to the point that a different reaction, involving breaking of the S-N bond, may occur.
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页码:1684 / 1686
页数:3
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