SYNTHESIS OF A PLATINUM COMPLEX WITH A DERIVATIVE OF MONOMERIC METATHIOPHOSPHORIC ACID AS ETA-2-LIGAND

被引：12

作者：

SCHERER, OJ

JUNGMANN, H

机构：

[1] Fachbereich Chemie der Universität, Kaiserslautern, D-6750

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909531

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first complex to contain a π‐bonded metathiophosphoric derivative has been prepared from R3C(SiR3)NP(S)NCR3 and L2Pt(C2H4). The two (CH3)3C groups are equivalent at room temperature; structure a was confirmed by X‐ray methods. Its dynamic behavior at low temperature can be explained by participation of form b with pentacoordinated silicon (R = CH3, L = PPh3). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：953 / 954

页数：2

共 4 条

[1] CUMULATED DOUBLE-BOND SYSTEMS AS LIGANDS .7. N,N'-DIARYLSULFURDIIMINE COMPLEXES OF NICKEL(0) AND PLANTINUM(0) OF TYPE [(PPH3)XM(RNSNR)]Y AND FORMATION OF A NOVEL COMPLEX [PTII[SN(1-NHR')(R)](PPH3)2] FROM [PT0(RNSNR)(PPH3)2], VIA AN IRREVERSIBLE INTRA-MOLECULAR REARRANGEMENT INVOLVING N-C(ARYL) BOND FORMATION AND N=S BOND BREAKINGL [J].