COORDINATION-COMPLEXES OF DI-2-THIENYLMERCURY AND DI-2-FURYLMERCURY

被引：6

作者：

BELL, NA

KING, RM

机构：

[1] Department of Chemistry, Sheffield City Polytechnic, Sheffield, S1 IWB, Pond Street

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)95214-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of di-2-furylmercury and its sulphur analogue with some monodentate and bidentate nitrogen, phosphorus and sulphur bases has been studied. Both organomercurials are relatively weak electron acceptors, the thienyl compound being weaker than the furyl compound, and only four complexes, (C4H3X)2Hg L (X = O, L = phen, tmp; X = O, S, L = dmp) * have been isolated. These represent the first reported examples of complexes formed by heterocyclic organomercury compounds, and their infrared, 1H NMR and mass spectra have been examined as well as their thermal behaviour. © 1979.

引用

页码：133 / 138

页数：6

共 24 条

[1]

Albert A, 1968, HETEROCYCLIC CHEM

[2]

BELL NH, UNPUBLISHED

[3]

CANOESQUIVEL M, 1977, AN QUIM, V73, P1051

[4]

CANTY AJ, 1973, J ORGANOMET CHEM, V49, P125