SOLUTION CONFORMATION AND INVERSION BARRIER IN PARA-TERT-BUTYL-25,27-DIHYDROXYCALIX[4]ARENE

被引:24
作者
GRYNSZPAN, F [1 ]
BIALI, SE [1 ]
机构
[1] HEBREW UNIV JERUSALEM,DEPT ORGAN CHEM,IL-91904 JERUSALEM,ISRAEL
关键词
D O I
10.1016/S0040-4039(00)93454-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Spectroscopic data indicate that the solution conformation of the dihydroxycalix[4]arene 3 (1,3-alternate) is intramolecularily hydrogen bonded and is different from the crystallographic conformation of its MeOH solvate (1,2-alternate).
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页码:5155 / 5158
页数:4
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