LIGAND-EXCHANGE CHROMATOGRAPHY OF RACEMATES .11. COMPLETE RESOLUTION OF SOME CHELATING RACEMIC COMPOUNDS AND NATURE OF SORPTION ENANTIOSELECTIVITY

被引：53

作者：

DAVANKOV, VA

ZOLOTAREV, YA

KURGANOV, AA

机构：

[1] Institute ox Organo-Element Compounds, Academy of Sciences, Moscow

来源：

JOURNAL OF LIQUID CHROMATOGRAPHY | 1979年 / 2卷 / 08期

关键词：

D O I：

10.1080/01483917908060130

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The results of a systematic study are summarized on chromatographic resolutions of racemic amino acids using ligand exchange on copper(ll) ion-charged polystyrene type resins containing residues of optically active proline Cl)? hydroxyproline (il), allo-hvdroxy-proline (ill) and azetidine carboxylic acid (iVj. Possible variants of the enantioselective complex formation in the resine phase are discussed. Several examples of quantitative resolutions of racemic amino acids as well as members of other classes of chelating organic compounds are giyen. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1191 / 1204

页数：14

共 12 条

[1] Davankov V.A., Seraechkin A.V., Ligand-Exchange Chromatography, J. Chromatogr., 141, (1977)
[2] Kurganov A.A., Zhuchkova L.Y., Davankov Y.A., Ligand-Exchange Chromatography of Racemates. X. Asymmetric Sorbents Based on Mono- and Diamines and Resolution of Racemates by Ligand-Exchange Chromatography, Makromoi. Chem., (1979)
[3] Bernauer K., Separating Racemates Using Column Chromatography on Optically Active Metal Complexes, (1971)
[4] Snyder R.V., Angelichi R.J., Meek R.B., Partial Resolution of Amino Acids by Column Chromatography on a Polystyrene Resin Containing an Optically Active Copper(II) Complex, J. Amer. Chem. Soc., 94, (1972)
[5] Tsuchida E., Nishikawa H., Terada E., The Resolution of α—Amino Acid by Chiral Polymer-Copper Complex, European Polymer J., 12, (1976)
[6] Lefebvre B., Audebert R., Quivoron C., Direct Resolution of Amino Acid Enantiomers by High Pressure Liquid Chromatography, Israel J. Chem., 15, (1977)
[7] Jozefonvicz J., Petit M.A., Szubarga A., Preparative Resolution of DL-Proline by Liquid Chromatography on a Polystyrene Resin Containing the L-Proline Copper(II), Complex, J. Chromatogr., 147, (1978)
[8] Muller D., Petit M.A., Szubarga A., Jozefonvicz J., Effect Stereoselectif du Derive N-Benzyl L-Pro-line dans la Formation de Complexes Metalliques Mixtes Associant l'Histidine, C. R. Acad. Sc. Paris, C, (1977)
[9] Based on a transcript of a lecture delivered at the 12th Inernational Symposium on Chromatography, (1978)
[10] Davankov V.A., Zolotarev Y.A., Ligand-Exchange Chromatography of Racemates, J. Chromatogr., (1978)

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