STRUCTURE OF TRANS-DIBROMO(ETHOXO)OXOBIS(TRIPHENYLPHOSPHINE)RHENIUM(V)

被引：30

作者：

LEBUIS, AM ^{[1
]}

ROUX, C ^{[1
]}

BEAUCHAMP, AL ^{[1
]}

机构：

[1] UNIV MONTREAL,DEPT CHIM,CP 6128,SUCC A,MONTREAL H3C 3J7,QUEBEC,CANADA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192004748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(OC-6-13)-Dibromo(ethoxo)oxobis(triphenylphosphine)rhenium(V), [ReBr2O(OC2H5)-{P(C6H5)3}2], M(r) = 931.66, monoclinic, C2/c, a = 12.284 (7), b = 14.509 (4), c = 19.308 (7) angstrom, beta = 93.33 (4)-degrees, V = 3435 (3) angstrom3, D(m)(293 K) = 1.82, D(x) = 1.801 Mg m-3, Z = 4, lambda(Mo Kalpha) = 0.71069 angstrom, mu(Mo Kalpha) = 6.03 mm-1, F(000) = 1816, T = 293 K, final R = 0.024 for 1515 unique observed reflections. The crystal contains approximately octahedral molecules of the trans-dibromo-trans-bis(phosphine) isomer. The linear O-Re-O unit lies on a twofold axis and the ethyl group of the ethoxo ligand is disordered over two orientations.

引用

页码：33 / 36

页数：4

共 24 条

[1] PREPARATIVE AND H-1-NMR SPECTROSCOPIC STUDIES ON PALLADIUM(II) AND PLATINUM(II) QUINOLINE-8-CARBALDEHYDE (1) COMPLEXES - X-RAY STRUCTURES OF THE CYCLOMETALATED ACYL COMPLEX PDCL(C(O)C9H6N)(PPH3).PPH3 AND TRANS-PTCL2(1)(PET3) [J].

ALBINATI, A ;

ANKLIN, CG ;

GANAZZOLI, F ;

RUEGG, H ;

PREGOSIN, PS .

INORGANIC CHEMISTRY, 1987, 26 (04) :503-508

[2] PREPARATION AND STRUCTURE OF A QUADRUPLY-BONDED DIMOLYBDENUM MIXED COMPLEX WITH ACETATE AND 7-AZAINDOLE LIGANDS [J].

ALLAIRE, F ;

BEAUCHAMP, AL .

INORGANICA CHIMICA ACTA, 1989, 156 (02) :241-249

[3] CRYSTAL-STRUCTURE OF A DIMERIC 1-METHYLCYTOSINE MERCURIC-CHLORIDE COMPLEX [J].

AUTHIERMARTIN, M ;

BEAUCHAMP, AL .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (07) :1213-1217

[4] THE STRUCTURE OF TRANS-DIBROMOOXO(N-PHENYLSALICYLIDENEIMINATO)-(TRIPHENYLPHOSPHINE)RHENIUM(V) [J].

BERTOLASI, V ;

SACERDOTI, M ;

GILLI, G ;

MAZZI, U .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (FEB) :426-429

[5] EFFICIENT SYNTHESES OF DIOXORHENIUM(V) COMPLEXES [J].

BREWER, JC ;

GRAY, HB .

INORGANIC CHEMISTRY, 1989, 28 (17) :3334-3336

[6] STUDIES OF METAL-NITROGEN MULTIPLE BONDS .V. CRYSTAL STRUCTURE OF POTASSIUM NITRIDOPENTACHLOROOSMATE(6) K2OSNCL5 [J].

BRIGHT, D ;

IBERS, JA .

INORGANIC CHEMISTRY, 1969, 8 (04) :709-&

[7] RHENIUM(V) OXIDE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPOUNDS TRANS-ETEI2O(OET)(PPH3)2,TRANS-MEEI2O(OME)(PPH3)2 AND OF THEIR HYDROLYSIS DERIVATIVE REIO2(PPH3)2 [J].

CIANI, GF ;

DALFONSO, G ;

ROMITI, PF ;

SIRONI, A ;

FRENI, M .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 72 (01) :29-37

[8] ANOMALOUS DISPERSION CORRECTIONS COMPUTED FROM SELF-CONSISTENT FIELD RELATIVISTIC DIRAC-SLATER WAVE FUNCTIONS [J].

CROMER, DT .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :17-&

[9] RELATIVISTIC CALCULATION OF ANOMALOUS SCATTERING FACTORS FOR X-RAYS [J].

CROMER, DT ;

LIBERMAN, D .

JOURNAL OF CHEMICAL PHYSICS, 1970, 53 (05) :1891-&

[10] CRYSTAL + MOLECULAR STRUCTURE OF TRIPHENYL-PHOSPHORUS [J].

DALY, JJ .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (OCT) :3799-&

← 1 2 3 →