STRUCTURE OF [BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE-P,P,P]CARBONYL-(PHENYLTHIOLATO)COBALT(I), [CO(PH2PCH2CH2P(PH)CH2CH2PPH2)(SPH)(CO)

被引：5

作者：

WEI, GW

HUANG, ZY

LEI, XJ

CAO, R

JIANG, FL

HONG, MC

LIU, HQ

机构：

[1] CHINESE ACAD SCI,FUZHOU LAB STRUCT CHEM,FUJIAN 350002,PEOPLES R CHINA

[2] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUJIAN 350002,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192003731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[CO(C34H33P3)(C6H5S)(CO)], M(r) = 730.68, monoclinic, P2(1), a = 11.163 (2), b = 15.499 (3), c = 10.427 (2) angstrom, beta = 94.18 (3)-degrees, V = 1799.34 (93) angstrom3, Z = 2, D(x) = 1.349 g cm-3, lambda(Mo Kalpha) = 0.71073 angstrom, mu = 6.928 cm-1, F(000) = 760, T = 296 K, final R = 0.043 for 1866 observed unique reflections. The compound is an asymmetric molecule with a five-coordinate Co atom. The Co-S, Co-C and average value of Co-P bond distances are 2.302 (3), 1.741 (9) and 2.160 (3) angstrom, respectively.

引用

页码：2130 / 2132

页数：3

共 7 条

[1] THIOLATO-COMPLEXES OF THE TRANSITION-METALS [J].