EFFECT OF BACKBONE FLEXIBILITY AND THE POSITION OF THE LATERAL GROUP ON THE MESOPHASE STABILITY OF LATERALLY ATTACHED, SIDE-CHAIN POLYMERS

被引：17

作者：

LEWTHWAITE, RA ^{[1
]}

GOODBY, JW ^{[1
]}

TOYNE, KJ ^{[1
]}

机构：

[1] UNIV HULL,SCH CHEM,HULL HU6 7RX,N HUMBERSIDE,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1993年 / 3卷 / 03期

关键词：

LIQUID CRYSTAL; POLYMER; LATERALLY ATTACHED POLYMER; POLYMER BACKBONE;

D O I：

10.1039/jm9930300241

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of chiral, nematic, laterally attached polymers from enantiotropic side-chain precursors is described. The effect of changing the point of attachment of the spacer group on the mesogenic core and the effect of the different natures of polysiloxane, polyacrylate and polymethacrylate backbones are discussed. The point of attachment of the lateral group is more significant for the monomer than for the polymer and the effects of the different polymer backbones in the side-chain systems are much reduced compared to the related polymers without side-chains.

引用

页码：241 / 245

页数：5

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