ION-CYCLOTRON RESONANCE STUDIES ON TERT-BUTYL, 2-NORBORNYL, AND 1-ADAMANTYL AND 2-ADAMANTYL CATIONS

被引：19

作者：

HOURIET, R

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-1000 BERLIN 12,FED REP GER

[2] ETH,INST PHYS CHEM,CH-1015 LAUSANNE,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 12期

关键词：

D O I：

10.1002/anie.197909511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The discussion about “classical”/“nonclassical”cations continues. ICR studies show that the 1‐adamantyl cation is certainly not exceptionally stabilized (as has been repeatedly suspected) and that the energy of the 2‐adamantyl cation differs by only 4 kcal/mol instead the expected amount of 16 kcal/mol. The analogy with the controversial 2‐norbornyl cation/2‐methyl‐2‐norbornyl cation system cannot be overlooked. Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：951 / 952

页数：2

共 14 条

[1] REACTIONS OF ATOMIC METAL-IONS WITH ALKYL-HALIDES AND ALCOHOLS IN THE GAS-PHASE [J].