COORDINATION CHEMISTRY OF BIS(3-AMINOPROPYL)PHENYLPHOSPHINE (BAP) - REACTIONS OF BAP WITH SOME D6 METAL-COMPLEXES OF MOLYBDENUM(0), TUNGSTEN(0) AND PLATINUM(IV)

被引:12
作者
BECKETT, MA
CASSIDY, DP
DUFFIN, AJ
机构
[1] Department of Chemistry, University of Wales, Bangor
关键词
D O I
10.1016/S0020-1693(00)80193-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Bis(3-aminopropyl)phenylphosphine (bap) has been reacted with fac-[{PtMe3I}4] in CHCl3 solution to yield fac-[PtMe3(bap)]I which has the bap ligand tridentate NNP. Metathesis of fac-[PtMe3(bap)]I with Na[BPh4] in thf solution results in fac-[PtMe3(bap)][BPh4]. Bap is also NNP tridentate in the Group 6 metal(0) complexes fac-[Mo(CO)3(bap)] and fac-[W(CO)3(bap)], prepared from the reactions of bap with cis-[M(CO)4(pip)2] (M = Mo, W). The new complexes have been characterized by melting point, elemental analysis, and by IR and multielement (H-1, B-11, P-31) NMR spectroscopy.
引用
收藏
页码:229 / 232
页数:4
相关论文
共 20 条