VARIABLE OXYGENATION LEVELS OF SULFUR IN STERICALLY HINDERED THIOLATES - MOLECULAR-STRUCTURE OF [N-(2-MERCAPTO-2-METHYLPROPYL)-N'-(2-SULFENO-2-METHYLPROPYL)-1,5-DIAZACYCLOOCTANATO]NICKEL(II)

被引：32

作者：

FONT, I ^{[1
]}

BUONOMO, R ^{[1
]}

REIBENSPIES, JH ^{[1
]}

DARENSBOURG, MY ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLL STN,TX 77843

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 26期

关键词：

D O I：

10.1021/ic00078a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first successful isolation of a nickel sulfoxide, NiS(=O)R, is attributed to the sterically encumbered sulfur sites in 4*. The NiS bond distance of a homologous series varies NiS(=O)R > NiSR > NiS(=O)(2)R. Despite a long (1.548(8)A)S-O bond in 4*, the oxygen is not easily removable, but rather 4* displays further O-atom uptake ability with both H2O2 and O-2.

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页码：5897 / 5898

页数：2

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