COPLANAR INTERDIGITATED BAND ELECTRODES FOR SYNTHESIS .1. OHMIC LOSS EVALUATION

被引：32

作者：

BELMONT, C ^{[1
]}

GIRAULT, HH ^{[1
]}

机构：

[1] ECOLE POLYTECH FED LAUSANNE,DEPT CHIM,ELECTROCHIM LAB,CH-1015 LAUSANNE,SWITZERLAND

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1994年 / 24卷 / 06期

关键词：

D O I：

10.1007/BF00249845

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new type of electrosynthesis cell consisting of coplanar interdigitated band electrodes is proposed. This approach permits minimization of the anode/cathode separation to a few hundred micrometres without hindering the hydrodynamics. In this paper, two analytical expressions are considered for the solution resistance between the bands. Results obtained for different geometries are compared to experimental data. It is shown that a substantial decrease in ohmic loss during synthesis can be achieved.

引用

页码：475 / 480

页数：6

共 17 条

[1] MICROARRAY ELECTROCHEMICAL FLOW DETECTORS AT HIGH APPLIED POTENTIALS AND LIQUID-CHROMATOGRAPHY WITH ELECTROCHEMICAL DETECTION OF CARBAMATE PESTICIDES IN RIVER WATER [J].

ANDERSON, JL ;

WHITEN, KK ;

BREWSTER, JD ;

OU, TY ;

NONIDEZ, WK .

ANALYTICAL CHEMISTRY, 1985, 57 (07) :1366-1373

[2]

Angot A., 1957, COMPLEMENTS MATH USA

[3] QUANTITATIVE-ANALYSIS OF REVERSIBLE DIFFUSION-CONTROLLED CURRENTS OF REDOX SOLUBLE SPECIES AT INTERDIGITATED ARRAY ELECTRODES UNDER STEADY-STATE CONDITIONS [J].

AOKI, K ;

MORITA, M ;

NIWA, O ;

TABEI, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 256 (02) :269-282

[4] HYDRODYNAMIC VOLTAMMETRY AT CHANNEL ELECTRODES .9. EDGE EFFECTS AT RECTANGULAR CHANNEL FLOW MICROELECTRODES [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 217 (01) :33-47

[5] DIGITAL-SIMULATION OF THE MEASURED ELECTROCHEMICAL RESPONSE OF REVERSIBLE REDOX COUPLES AT MICROELECTRODE ARRAYS - CONSEQUENCES ARISING FROM CLOSELY SPACED ULTRAMICROELECTRODES [J].

BARD, AJ ;

CRAYSTON, JA ;

KITTLESEN, GP ;

SHEA, TV ;

WRIGHTON, MS .

ANALYTICAL CHEMISTRY, 1986, 58 (11) :2321-2331

[6]

CARLSAW HS, 1959, CONDUCTION HEAT SOLI

[7]

Coeuret F., 1993, ELEMENTS GENIE ELECT, V2nd

[8]

FLEISCHMAN M, 1987, ULTRAMICROELECTRODES

[9] USE OF CONFORMAL-MAPS TO MODEL THE VOLTAMMETRIC RESPONSE OF COLLECTOR GENERATOR DOUBLE-BAND ELECTRODES [J].

FOSSET, B ;

AMATORE, CA ;

BARTELT, JE ;

MICHAEL, AC ;

WIGHTMAN, RM .

ANALYTICAL CHEMISTRY, 1991, 63 (04) :306-314

[10]

Genders D.J, 1990, ELECTROSYNTHESIS LAB

← 1 2 →