EXCESS VOLUMES OF MIXING OF BINARY-MIXTURES OF ARSENIC TRIBROMIDE WITH BENZENE, CYCLOHEXANE, AND CARBON-TETRACHLORIDE AT 303.15, 308.15, AND 313.15-K

被引：11

作者：

MAHESHWARI, RC ^{[1
]}

SURI, SK ^{[1
]}

TEWARI, US ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,BOMBAY 400076,INDIA

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1979年 / 24卷 / 03期

关键词：

D O I：

10.1021/je60082a022

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Excess volumes, VE, of binary mixtures of arsenic tribromide with benzene, cyclohexane, and carbon tetrachloride have been calculated from experimental density data at 303.15, 308.15, and 313.15 K over the entire composition range. The VE for solutions of arsenic tribromide with benzene are negative indicating the strong intermolecular interactions between the components resulting in the formation of a 1: 1 charge-transfer type complex. For the other two binary mixtures VE is positive. VE decreases with an increase of temperature for the binary mixtures studied. © 1979, American Chemical Society. All rights reserved.

引用

页码：237 / 239

页数：3