PERFLUORO-ENOLATE CHEMISTRY - AN ELECTROPHILE-COEXISTING PROCEDURE FOR CARBON-CARBON BOND FORMING REACTIONS WITH AN ESTER LITHIUM F-ENOLATE

被引：23

作者：

QIAN, CP ^{[1
]}

NAKAI, T ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM TECHNOL,MEGURO KU,TOKYO 152,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(00)97238-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel "electrophile-coexisting" procedure is developed for effecting aldol reactions and Michael additions with the lithium F-enolate of ethyl tetrafluoropropionate without appreciable occurrence of defluorination from the F-enolate. © 1990.

引用

页码：7043 / 7046

页数：4

共 8 条

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[6] KETONE PERFLUOROENOLATES - REGIOSELECTIVE AND STEREOSELECTIVE SYNTHESIS, UNIQUE REACTIVITIES, AND ELECTRONIC-PROPERTIES [J].

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[8] (TRIFLUOROMETHYL)KETENE SILYL ACETAL AS AN EQUIVALENT TO THE TRIFLUOROPROPIONIC ESTER ENOLATE - PREPARATION AND ALDOL-TYPE REACTIONS WITH ACETALS [J].

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TETRAHEDRON LETTERS, 1984, 25 (36) :3987-3990

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