SYNTHESIS AND ENANTIOMER RECOGNITION OF THE 18-CROWN-6 DERIVATIVE CONTAINING 2 TERT-BUTYL SUBSTITUENTS AS A CHIRAL BARRIER

被引：8

作者：

NAEMURA, K

UENO, M

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 12期

关键词：

D O I：

10.1246/bcsj.63.3695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The optically active 18-crown-6 derivative having two tert-butyl substituents as a chiral barrier was prepared by using (-)-(R)-3,3-dimethylbutane-1,2-diol as a chiral source and its chiral recognition behavior in transport of racemic guest molecules through bulk liquid membranes was investigated.

引用

页码：3695 / 3697

页数：3

共 5 条

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DALLEY, NK
IZATT, RM
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[2] Gokel G. W., 1982, MACROCYCLIC POLYETHE
[3] GUETTE JP, 1972, B SOC CHIM FR, P4217
[4] SYNTHETIC CHIRAL MACROCYCLIC CROWN LIGANDS - A SHORT REVIEW
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BRADSHAW, JS
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[J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1982, 19 (01) : 3 - 19
[5] HOST-GUEST COMPLEXATION .20. CHIRAL RECOGNITION IN TRANSPORT AS A MOLECULAR-BASIS FOR A CATALYTIC RESOLVING MACHINE
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